作者:Lu Xiaodong
出版項:Ann Arbor, Mich. : UMI, 2003
載體形態:
分類號:TB304
語種:英文
關鍵詞:refractory corrosion
內容簡介Properties of nuclear waste melts and glasses : contact-refractory corrosion and vapor phase hydration 核廢料熔體和玻璃的性能:接觸-耐火材料侵蝕和氣相水化 摘要: 廢料玻璃熔體對耐火材料侵蝕的控制和Hanford低活性廢料(LAW)玻璃產物要求的的氣相水化試驗(VHT)是核廢料玻璃化遇到的許多技術挑戰中的其中兩個最為關鍵的問題。 在本研究中,把耐火材料侵蝕看作非平衡、多組分和多相反應的傳輸過程的復合體,從熱力學和動力學去研究。粒狀耐火材料在不飽和熔體的溶解試驗加上過飽和熔體的結晶試驗用來確定可能的平衡點。 In this study, refractory corrosion was treated as a complex non-equilibrium, multi-component and multi-phase reactive transport process and studied both thermodynamically and kinetically. Dissolution tests of granular refractory materials into under-saturated melts coupled with crystallization tests from supersaturated melts were used to determine the possible equilibrium points. The test results show that spinet phase is the most stable phase of K-3 refractory. ........
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