作者：Kate Black;Paul R. Chalker;Anthony C. Jones;Peter J. King;John L. Roberts;Peter N. Heys;
作者單位：Department of Chemistry, University of Liverpool Liverpool, Merseyside, L69 7ZD (UK);Department of Chemistry, University of Liverpool Liverpool, Merseyside, L69 7ZD (UK);Department of Chemistry, University of Liverpool Liverpool, Merseyside, L69 7ZD (UK);
刊名：Chemical vapor deposition
ISSN：0948-1907
出版年：2010-01-05
卷：16
期：40911
起頁：106
止頁：111
分類號：TQ175
語種：英文
關鍵詞：dimethylzinc adducts;liquid injection MOCVD;ZnO nanowires;
內容簡介The oxygen donor adducts of dimethylzinc [Me2Zn(L)] (Ltetrahydrofuran, tetrahydropyran, or furan) are used without pre-reaction with oxygen for the growth of ZnO by liquid injection metal-organic (MO)CVD over the temperature range 350–550 8C. Vertically-aligned ZnO nanowires are deposited in a narrow temperature range centered on 500 8C. At other deposition temperatures, the ZnO films show continuous polycrystalline morphologies. At room temperature, the ZnO nanowires exhibit intense near band-edge photoluminescence (PL) at emission energies of 3.26 to 3.28 eV, and show minimal defect-related visible emission. Analysis of the ZnO nanowires by Auger electron spectroscopy (AES) shows that they are of high purity, with carbon not detected at an estimated detection limit of 0.5 at..
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